2 4-dinitrophenylhydrazine
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2,4-Dinitrophenylhydrazine can be used to qualitatively detect the carbonyl functionality of a ketone or aldehyde functional group. A positive test is signaled by a yellow or red precipitate (known as a dinitrophenylhydrazone):
RR'C=O + C6H3(NO2)2NHNH2 → C6H3(NO2)2NHNCRR' + H2O
This reaction can be described as a condensation reaction, with two molecules joining together with loss of water. It is also called addition-elimination reaction: nucleophilic addition of the -NH2 group to the C=O carbonyl group, followed by the removal of a H2O molecule.
[ 本帖最後由 雪代緣 於 2008-3-18 11:50 AM 編輯 ]
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